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Porous metal-organic truncated octahedron constructed from paddle-wheel squares and terthiophene links.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Ni, Zheng Yassar, Abderrahim Antoun, Tarek Yaghi, Omar M. |
| Copyright Year | 2005 |
| Abstract | A metal-organic truncated octahedron (termed MOP-28) has been constructed from six rigid square-shaped Cu2(CO2)4 paddle-wheel building units and twelve 2,2':5',2' '-terthiophene-5,5' '-dicarboxylate (TTDC) linkers. TTDC linker in the cis,cis conformation provides the critical 90 degrees linkage for this unique construction. The porous structure of MOP-28 is maintained even after the removal of guest species, as evidenced by this compound's nitrogen sorption isotherm of Type I characteristics and unprecedented surface area (Langmuir surface area 1100 m2/g, BET surface area 914 m2/g) among materials composed of discrete molecules. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/ja052055c |
| PubMed reference number | 16159240 |
| Journal | Medline |
| Volume Number | 127 |
| Issue Number | 37 |
| Alternate Webpage(s) | http://yaghi.berkeley.edu/pdfPublications/Terthiophene.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/ja052055c |
| Journal | Journal of the American Chemical Society |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
