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Carbonate extraction-based refining of uranium. Separation of U(VI), Ce(IV), and Ln(III) from aqueous carbonate solutions with methyltrioctylammonium carbonate
| Content Provider | Semantic Scholar |
|---|---|
| Author | Boyarintsev, A. V. Abashev, L. M. Stepanov, Sergey I. Zhilov, Valerii I. Chekmarev, A. M. Tsivadze, Aslan Yu. |
| Copyright Year | 2017 |
| Abstract | The extraction of U(VI), Ce(IV), La(III), Nd(III), Sm(III), and Y(III) from an aqueous solution of Na2CO3 (0.25 mol/L) resulting from oxidative dissolution of U(IV) in the presence of H2O2 into a solution of methyltrioctylammonium carbonate (0.25 mol/L) in toluene. It was found that βU(VI)/Ln(III) values vary from ~8 to 3290 as the O : W ratio changes from 2 : 1 to 10 : 1, while βU(VI)/Ce(IV) varies from ~1.5 to 10, which allows for the extraction separation of U(VI) from Ce(IV) in a 8- to 10-stage counter-current extraction cascade and from Ln(III) in 2- to 3-stage cascade under the same conditions. |
| Starting Page | 70 |
| Ending Page | 73 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1134/S0012500817040024 |
| Volume Number | 473 |
| Alternate Webpage(s) | https://page-one.springer.com/pdf/preview/10.1134/S0012500817040024 |
| Alternate Webpage(s) | https://doi.org/10.1134/S0012500817040024 |
| Journal | Doklady Chemistry |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |