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Stabilisation of a triply-bridging cyclopentadienyl ligand in a tetrapalladium cluster.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Monakhov, Kirill Yu Gourlaouen, Christophe Braunstein, Pierre |
| Copyright Year | 2012 |
| Abstract | An unusual triply-bridging cyclopentadienyl (C(5)H(5) = Cp) ligand has been characterised in the tetranuclear palladium cluster [Pd(3)(II)(μ-OAc)(4)(μ(3)-Cp)Pd(0)(η(5)-Cp)] (1). It is coordinated in the μ(3)-η(1):η(2):η(2) mode to a [Pd(3)](4+) triangular subunit of the mixed-valence cluster 1. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c2cc32886k |
| PubMed reference number | 22737690 |
| Journal | Medline |
| Volume Number | 48 |
| Issue Number | 67 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cc/c2/c2cc32886k/c2cc32886k.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/c2cc32886k |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |