NDLI: ECL performance of ruthenium tris-bipyridyl complexes covalently linked with phenothiazine through different bridge.

Content Provider	Semantic Scholar
Author	Sun, Shiguo Yang, Y. L. Liu, Fengyu Fan, Jiangli Kehr, J. C. Sun, Licheng Peng, Xiaojun
Copyright Year	2010
Abstract	Three ruthenium complexes 1a, 1b and 1c were synthesized, in which the phenothiazine moiety was covalently linked to the ruthenium complex through a 4 carbon chain and amide bond, respectively. The results demonstrate that one PTZ moiety is preferred to reach a good ECL performance, and the 4 carbon chain linked complex 1a exhibits the highest ECL enhancement (up to about 9 times), in comparison with the commonly utilized parent Ru(bpy)(3)(2+), permitting a lower detection limit of 1.0 x 10(-14) M with signal to noise of 3 for 20 mM DBAE at Au electrode.
File Format	PDF HTM / HTML
DOI	10.1039/c0dt00279h
PubMed reference number	20714621
Journal	Medline
Volume Number	39
Issue Number	37
Alternate Webpage(s)	http://www.rsc.org/suppdata/dt/c0/c0dt00279h/c0dt00279h.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c0dt00279h
Journal	Dalton transactions
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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