NDLI: Asymmetric carbon-carbon bond formation gamma to a carbonyl group: phosphine-catalyzed addition of nitromethane to allenes.

Content Provider	Semantic Scholar
Author	Smith, Sean Wesley Fu, Gregory C.
Copyright Year	2009
Abstract	A chiral phosphine catalyzes the addition of a carbon nucleophile to the gamma position of an electron-poor allene (amide-, ester-, or phosphonate-substituted), in preference to isomerization to a 1,3-diene, in good ee and yield. This strategy provides an attractive method for the catalytic asymmetric gamma functionalization of carbonyl (and related) compounds.
File Format	PDF HTM / HTML
DOI	10.1021/ja9061823
PubMed reference number	19772285
Journal	Medline
Volume Number	131
Issue Number	40
Alternate Webpage(s)	http://dspace.mit.edu/openaccess-disseminate/1721.1/67692
Alternate Webpage(s)	http://dspace.mit.edu/bitstream/handle/1721.1/67692/nihms147483.pdf;jsessionid=A87BB04C9179AC27CA35AFBFE3FF330F?sequence=1
Alternate Webpage(s)	https://doi.org/10.1021/ja9061823
Journal	Journal of the American Chemical Society
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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