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Intramolecular Pd(II)-catalyzed aerobic oxidative amination of alkenes: synthesis of six-membered N-heterocycles.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Lu, Zhan Stahl, Shannon S. |
| Copyright Year | 2012 |
| Abstract | Use of a base-free Pd(DMSO)(2)(TFA)(2) catalyst system enables the synthesis of six-membered nitrogen heterocycles via a Wacker-type aerobic oxidative cyclization of alkenes bearing tethered sulfonamides. Various heterocycles, including morpholines, piperidines, piperazines, and piperazinones, are accessible by this method. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/ol300030w |
| PubMed reference number | 22356620 |
| Journal | Medline |
| Volume Number | 14 |
| Issue Number | 5 |
| Alternate Webpage(s) | http://stahl.chem.wisc.edu/sites/stahl.chem.wisc.edu/files/publications/12OL%20Lu%20SI.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/ol300030w |
| Journal | Organic letters |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |