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Kinetics of Oxidation of Lactic, Mandelic & Benzilic Acids by Trichloroisocyanuric Acid in Aqueous Acetic Acid Media
| Content Provider | Semantic Scholar |
|---|---|
| Author | Radhakrishnamurti, P. S. Rath, Nabeen Kumar Panda, Ram Krishna |
| Copyright Year | 1988 |
| Abstract | Oxidation of lactic, mandelic and benzilic acids by trichloroisocyanuric acid (TCICA) in aqueous acetic acid-acid media is pseudo-first order in [TC1CA]"both in the absence and presence of added Cl.The rate constants show a linear dependence on [substrate]. Thereactiori remains unaffected at lowerjl-l + ](0.1 x 10-2-2 x 102 mol dm -J); but increases linearly at higher [H +] ( lOx 102-40 x 10 2mol dm J). Increase in dielectric constant of the medium has a negligible effect on the reaction rate. Although kOh' consistently increases with increase in [CIlad' the magnitude of increase is rather small. The reaction most probably proceeds through a concerted oxidative decarboxylation mechanism leading to a carbonyl derivative and CO, as the primary oxidation products. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://nopr.niscair.res.in/bitstream/123456789/47397/1/IJCA%2027A(11)%20963-967.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
