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Pyrocatechol Violet immobilized Amberlite XAD-2: synthesis and metal-ion uptake properties suitable for analytical applications
| Content Provider | Semantic Scholar |
|---|---|
| Author | Saxena, Reena Singh, Ajai Kumar |
| Copyright Year | 1997 |
| Abstract | Abstract Amberlite XAD-2 has been functionalized by coupling it, through the NN group, with Pyrocatechol Violet (PV), and the resulting resin has been characterized by elemental analysis, thermogravimetric analysis (TGA) and IR spectra. The resin has been used for preconcentrating Zn(II), Cd(II), Pb(II) and Ni(II) ions prior to their determination by flame atomic absorption spectrometry. The optimum pH values for quantitative sorption are 5, 5–7, 4, and 3 for Zn, Cd, Pb and Ni, respectively. The four metals can be desorbed (recovery ~98%) with 4 M HNO 3 ; also, 4 M HCl is equally suitable except for Zn. The sorption capacity of the resin is 1410, 1270, 620 and 1360 μg g −1 resin for Zn, Cd, Ni and Pb, respectively. The effect of F − , Cl − , NO 3 − , SO 4 2− and PO 4 3− on the sorption of these four metal ions has been investigated. They are tolerable in the range 0.01–0.20 M, for Pb. In the sorption of Zn(II) and Ni(II), the tolerance limits of all these ions are upto 0.01 M, whereas for Cd(II), F − , NO 3 − , and PO 4 3− have been found to be tolerable upto 0.50, 0.10 and 0.10 M, respectively. The preconcentration factors are 60, 50, 23 and 18 for Zn, Cd, Pb and Ni, respectively. Simultaneous collection and determination of the four metals are possible. Cations commonly present in drinking water do not affect the sorption of either metal ion if present at a concentration level similar to that of water. The method has been applied to determine Zn, Ni and Pb content of well-water samples (RSD ≤9%). |
| Starting Page | 285 |
| Ending Page | 290 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1016/S0003-2670(96)00515-6 |
| Volume Number | 340 |
| Alternate Webpage(s) | http://eprint.iitd.ac.in/bitstream/2074/328/1/saxenapyr97.pdf |
| Alternate Webpage(s) | https://doi.org/10.1016/S0003-2670%2896%2900515-6 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
