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Of the Oxygen Electrode Reaction Using Mixed Conducting Oxide Surface Layers . Part Ii : Small Signal Analysis
| Content Provider | Semantic Scholar |
|---|---|
| Author | Vries, Kees Jan De |
| Copyright Year | 2002 |
| Abstract | The oxygen gas electrode has been studied for a number of mixed conducting oxide surface layers on top of Gd2Zr20 I (TGZO) solid electrolytes. In part II of this paper we present the results of frequency dispers on measurements for the electrode reaction, supplying additional information to the results of current-overvoltage experiments presented in part I. For both kinds of experiments the same trends were observed for the electrode polarization. Best results are obtained for a surface layer of TGZO, while p-type mixed conducting oxides give less decreased values of the electrode polarization. High electrode capacitances were found in the case of mixed conducting surface layers (about 700 F/m2). The electrode reactions follow a Butler-Volmer type of equation. Most probably a diffusion process is rate controlling the overall charge transfer process. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://doc.utwente.nl/69600/1/Dijk86study2.pdf |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Behavior Biological specimen CDISC SEND Biospecimens Terminology Characteristic impedance Electric Capacitance Electrolytes Experiment Greater Ionic Linear programming relaxation Mike Lesser Mixed conductor Oxides Oxygen Polarization (waves) Pseudo brand of pseudoephedrine Quantitative impedance Signal Frequency Signal processing Small-signal model anatomical layer |
| Content Type | Text |
| Resource Type | Article |