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source of the anomalous stability of bis-peroxides †
| Content Provider | Semantic Scholar |
|---|---|
| Author | Gomes, Gabriel Dos Passos Vil, Vera Terent'evb, Alexander Alabugin, Igor V. |
| Copyright Year | 2015 |
| Abstract | The unusual stability of bisand tris-peroxides contradicts the conventional wisdom – some of them canmelt without decomposition at temperatures exceeding 100 C. In this work, we disclose a stabilizing stereoelectronic effect that two peroxide groups can exert on each other. This stabilization originates from strong anomeric nO / s*CO interactions that are absent in mono-peroxides but reintroduced in molecules where two peroxide moieties are separated by a CH2 group. Furthermore, such effects can be induced by other s-acceptors and amplified by structural constraints imposed by cyclic and bicyclic frameworks. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2015/sc/c5sc02402a |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
