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Mesoporous carbon-carbon nanotube-sulfur composite microspheres for high-areal-capacity lithium-sulfur battery cathodes.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Xu, Terrence Song, Jiangxuan Gordin, Mikhail L. Sohn, Hiesang Yu, Zhaoxin Chen, Shuru Wang, Donghai |
| Copyright Year | 2013 |
| Abstract | Lithium-sulfur (Li-S) batteries offer theoretical energy density much higher than that of lithium-ion batteries, but their development faces significant challenges. Mesoporous carbon-sulfur composite microspheres are successfully synthesized by combining emulsion polymerization and the evaporation-induced self-assembly (EISA) process. Such materials not only exhibit high sulfur-specific capacity and excellent retention as Li-S cathodes but also afford much improved tap density, sulfur content, and areal capacity necessary for practical development of high-energy-density Li-S batteries. In addition, when incorporated with carbon nanotubes (CNTs) to form mesoporous carbon-CNT-sulfur composite microspheres, the material demonstrated superb battery performance even at a high current density of 2.8 mA/cm(2), with a reversible capacity over 700 mAh/g after 200 cycles. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/am4035784 |
| PubMed reference number | 24090278 |
| Journal | Medline |
| Volume Number | 5 |
| Issue Number | 21 |
| Alternate Webpage(s) | http://www.mne.psu.edu/dwang/publication/46.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/am4035784 |
| Journal | ACS applied materials & interfaces |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |