NDLI: First total synthesis of concavine† †Electronic supplementary information (ESI) available. CCDC 1523963. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc05627j Click here for additional data file. Click here for additional data file.

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First total synthesis of concavine† †Electronic supplementary information (ESI) available. CCDC 1523963. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc05627j Click here for additional data file. Click here for additional data file.

Content Provider	Semantic Scholar
Author	Saint-Dizier, François Simpkins, Nigel S.
Copyright Year	2017
Abstract	The synthesis of the unusual alkaloid concavine, isolated from Clitocybe concava (Basidiomycetae), has been accomplished. The synthetic route features regioand stereoselective manipulation of polycyclic imide intermediates via enolate substitution and Grignard addition, along with a key bridge forming step involving a new method for sulfenylative radical cyclisation. The NMR data for synthetic concavine demonstrate that the original data reported for the natural product refer to the derived acetic acid salt, probably formed as an artefact of isolation or purification.
Starting Page	3384
Ending Page	3389
Page Count	6
File Format	PDF HTM / HTML
PubMed reference number	28507709
Volume Number	8
Alternate Webpage(s)	http://www.rsc.org/suppdata/c6/sc/c6sc05627j/c6sc05627j1.pdf
Journal	Chemical Science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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