Design and construction of coordination polymers based on 2,2′-dinitro-4,4′-biphenyldicarboxylate and imidazole-based ligands: The effect of ligand length and metal ions

Content Provider	Semantic Scholar
Author	Li, Baiyan Zhou, Xiaojing Zhou, Qi Li, Guanghua Li, Yijin Shi, Zhan Feng, Shouhua
Copyright Year	2011
Abstract	Five coordination polymers, Mn4(nbpdc)4(bip)(H2O)2 (1), Co5(nbpdc)4(bip)2(H2O)6(OH)2 (2), Cu5(nbpdc)4(bip)2(H2O)2(OH)2 (3), Zn5(nbpdc)4(bip)2(OH)2 (4), and Cd2(nbpdc)2(bip) (5), (H2nbpdc = 2,2′-dinitro-4,4′-biphenyldicarboxyl acid, bip = 1,5-bis(imidazole)pentane), have been prepared and structurally characterized. In these compounds, nbpdc and bip link different secondary building units (SBUs) to construct a variety of architectures based on different metals. Compound 1 presents a 3D hex net based on infinite rod-shaped SBUs. Compound 2 shows a 3D framework with mab topology based on Co5 clusters and exhibits an interesting self-penetration feature. Compound 3 presents a 3D framework with pcu topology constructed by Cu5 clusters. Compound 4 is a 3D framework with pcu topology based on infinite rod-shaped SBUs. Compound 5, like compound 4, also exhibits pcu topology constructed by rod-shaped SBUs, but they both possess different structures. The magnetic properties of compounds 1 and 2 have been characterized.
Starting Page	4592
Ending Page	4598
Page Count	7
File Format	PDF HTM / HTML
DOI	10.1039/C1CE05061C
Volume Number	13
Alternate Webpage(s)	http://www.rsc.org/suppdata/ce/c1/c1ce05061c/c1ce05061c.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C1CE05061C
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article