NDLI: Redox-active tubular frameworks with TTF: self-assemblies by complementary hydrogen-bonds and π-stacks of TTF-phenyluracil

Content Provider	Semantic Scholar
Author	Murata, Tsuyoshi Maki, Suguru Ohmoto, Makoto Miyazaki, Eigo Umemoto, Yoshikazu Nakasuji, Kazuhiro Morita, Yasushi
Copyright Year	2011
Abstract	Tubular frameworks of a tetrathiafulvalene (TTF) based electron-donor with a N1-phenyluracil moiety were constructed by strong self-assembling abilities. The uracil moiety formed the reversed Watson–Crick type hydrogen-bond pair. The TTF moiety exhibited C–H⋯X hydrogen-bonds, S⋯S interactions, and uniform π-stack. The phenyl group formed a herring-bone array by the edge-to-face interaction. These multiple intermolecular interactions established channels of ca. 4 × 8 A. The cavities were filled with crystalline solvent molecules (tetrahydrofuran and pyridine), which were fixed on the framework by the C–H⋯X hydrogen-bonds.
Starting Page	6880
Ending Page	6884
Page Count	5
File Format	PDF HTM / HTML
DOI	10.1039/C1CE05794D
Volume Number	13
Alternate Webpage(s)	http://www.rsc.org/suppdata/ce/c1/c1ce05794d/c1ce05794d.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C1CE05794D
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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