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End group modification of poly(acrylates) obtained via ATRP: a user guide
| Content Provider | Semantic Scholar |
|---|---|
| Author | Anastasaki, Athina Willenbacher, Johannes Fleischmann, Carolin Gutekunst, Will R. Hawker, Craig J. |
| Copyright Year | 2017 |
| Abstract | The versatile and high yielding functionalization of polymer end groups is a critical tool for controlling material properties and/or for successful post polymerization reactions. In this report, bromine-terminated poly(methyl acrylate) derivatives are used as a model system for identifying conditions leading to quantitative transformation of the end group. A wide range of small molecules and associated reactions for the introduction of specific acidic, basic, hydrophilic or hydrophobic functionality are described. Analysis by SEC, 1H NMR and MALDI-ToF-MS provides evidence for full conversion of the end group. The user-friendly nature of these procedures serve as a powerful strategy for the synthesis of end functionalized polymers. |
| Starting Page | 689 |
| Ending Page | 697 |
| Page Count | 9 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C6PY01993E |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c6/py/c6py01993e/c6py01993e1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C6PY01993E |
| Volume Number | 8 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
