Multiphase equilibrium flash with salt precipitation in systems with multiple salts

Content Provider	Semantic Scholar
Author	Lucia, Angelo Henley, Heath Thomas, Edward
Copyright Year	2015
Abstract	A new methodology for determining simultaneous chemical and phase equilibrium of mixtures of light gases and aqueous electrolyte solutions with the potential for multiple salt deposition is proposed. The novel aspects of this new approach include, but are not limited to (1) a novel tearing algorithm for determining equilibrium ion solubility limits, (2) rigorous proof that the proposed tearing algorithm generates a Cauchy sequence and is therefore guaranteed to converge to the correct equilibrium ion solubility limits (3) and a unique formulation of the combined chemical and multi-phase equilibrium flash problem that accounts for salt deposition but decouples the chemical and phase equilibrium aspects of the flash. Examples from real EOR and CO2 sequestration applications are presented. Results clearly show that the proposed numerical approach is reliable, robust, and efficient and can be used to determine salt deposition in multi-phase flash problems. Several geometric illustrations and numerical details are used to elucidate key points of the proposed approach. © 2014 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
File Format	PDF HTM / HTML
Alternate Webpage(s)	https://web.uri.edu/cheme/files/GHCeos6.pdf
Language	English
Access Restriction	Open
Subject Keyword	Carbon Dioxide Chemical vapor deposition Converge ER-overload response Engineering European ordering rules Gases Ions Multiple Myeloma Nash equilibrium Numerical analysis Numerous Physical vapor deposition Salts Scientific Publication Solutions algorithm mixture
Content Type	Text
Resource Type	Article