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A cascade radical-mediated macrocyclisation–transannulation approach to oestrogen steroids
| Content Provider | Semantic Scholar |
|---|---|
| Author | Cardente, Miguel Angel González McCulloch, Stuart Pattenden, Gerald |
| Copyright Year | 2001 |
| Abstract | Abstract A new approach to ring A aromatic steroids, based on cascade 13- endo - trig/dig macrocyclisations followed by sequential 5- exo-trig and 6- exo-trig transannulations, exemplified in the syntheses of the cis,anti,trans tetracycle 9 and the trans,syn tetracycle 13 from the ortho -substituted aryl polyen(yne) precursors, 8 and 12 respectively, is described. |
| Starting Page | 571 |
| Ending Page | 574 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1016/S1387-1609(01)01271-3 |
| Volume Number | 4 |
| Alternate Webpage(s) | https://www.uv.es/gonzalma/articles/comptes.pdf |
| Alternate Webpage(s) | https://doi.org/10.1016/S1387-1609%2801%2901271-3 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |