Structures and sorption properties of the coordination polymers built up of 3d metal carboxylate polynuclear complexes

Content Provider	Semantic Scholar
Author	Polunin, R. A. Kolotilov, S. V. Kiskin, M. A. Gavrilenko, K. S. Ouahab, Lahcen Eremenko, I. L. Novotortsev, V. N. Pavlishchuk, V. V.
Copyright Year	2010
Abstract	The reaction of trinuclear acetate complexes Fe2MO(AcO)6(H2O)3 (M = Ni2+, Co2+) with 4,4′-bipyridine (bpy) results, depending on the reaction conditions, in porous coordination polymers with the composition Fe2MO(AcO)6(bpy)1.5 (with retention of the metal core Fe2MO(AcO)6) or nonporous coordination polymers with the composition M2(AcO)4(bpy)2 (with destruction of the metal core Fe2MO(AcO)6). The adsorption and desorption properties of the compounds Fe2MO(AcO)6(bpy)1.5 with respect to nitrogen and hydrogen were studied. The reaction of hexanuclear benzoate complex Mn6O2(PhCOO)10(MeCN)4 with bpy or trans-1,2-bis(4-pyridyl)ethylene (bpe) in DMF results in destruction of the metal core Mn6O2(PhCOO)10 and formation of nonporous coordination polymers, while the pivalate complex Mn6O2(Piv)10(EtOH)3(HPiv) under the same conditions gives rise to the coordination polymer containing Mn6O2(Piv)10 structural blocks.
Starting Page	1217
Ending Page	1224
Page Count	8
File Format	PDF HTM / HTML
DOI	10.1007/s11172-010-0224-y
Alternate Webpage(s)	https://page-one.springer.com/pdf/preview/10.1007/s11172-010-0224-y
Alternate Webpage(s)	https://doi.org/10.1007/s11172-010-0224-y
Volume Number	59
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article