Loading...
Please wait, while we are loading the content...
Similar Documents
Structural Characterization of Cadmium Hexacyanometallates(II) and Related Complexes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Reguera, E. Gómez, Ariel Tovar Balmaseda, Jorge Contreras, Gustavo Escamilla, Ana Laura López |
| Copyright Year | 2001 |
| Abstract | Cadmium hexacyanometallates (II) crystallize in the same monoclinic cell (space group C52h−P21/n) reported for the analogs of manganous complexes. In that monoclinic framework, two outer cations (M = Mn2+ or Cd2+) of neighboring structural units M2[LII(CN)6], (L = FeII, RuII, OsII), are linked by two common water molecules. On heating above 100°C, these water bridges are removed. In dehydrated complexes, the outer cation (M) remains linked to only three CN ligands. The loss of aquo-ligands induces a remarkable π-back donation from the inner cation (L) to CN ligands, which was studied using IR, Raman, and Mössbauer spectroscopies. |
| Starting Page | 59 |
| Ending Page | 66 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| DOI | 10.1023/A:1009262118721 |
| Volume Number | 12 |
| Alternate Webpage(s) | https://www.repositoriodigital.ipn.mx/bitstream/123456789/11695/1/2001StrChemHexaCd%201.pdf |
| Alternate Webpage(s) | https://doi.org/10.1023/A%3A1009262118721 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
