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Hydrosilylation of Aldehydes and Ketones Catalyzed by Nickel PCP-Pincer Hydride Complexes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Chakraborty, Sumit Krause, Jeanette A. Guan, Hairong |
| Copyright Year | 2009 |
| Abstract | Nickel PCP-pincer hydride complexes catalyze chemoselective hydrosilylation of C═O bonds of aldehydes and ketones in the presence of other functional groups. The mechanism involves C═O insertion into a nickel−hydrogen bond, followed by cleavage of the newly formed Ni−O bond with a silane. |
| Starting Page | 582 |
| Ending Page | 586 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/om800948f |
| Volume Number | 28 |
| Alternate Webpage(s) | http://webcentral.uc.edu/eProf/media/attachment/eprofmediafile_501.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/om800948f |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |