Loading...
Please wait, while we are loading the content...
Similar Documents
Principles of interaction of furazano-1,2,3,4-tetrazine-1,3-dioxide with organic solvents
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zelenov, V. P. Kalmykov, P. I. Kalashnikov, A. I. |
| Copyright Year | 2013 |
| Abstract | Physicochemical interactions of furazano-1,2,3,4-tetrazine-1,3-dioxide (F) with organic solvents are studied according to thermogravimetry and UV spectrophotometry. It is shown that the donor-acceptor interaction of F with aromatic hydrocarbons is observed with the formation of mobile complexes. The solubility of F is determined in a series of organic and aqueous-organic media in the temperature range of 0 to 72°C. In an acetic acid-water system, the synergetic temperature effect of an increase in solubility is revealed for F, and the maximum solubility of F is found at 70°C and an F : AcOH : H2O molar ratio of 2 : 1 : 1. For solutions of F in dichloromethane, a solvotropic effect is observed in the presence of 2,4-dinitro-2,4-diazapentane. |
| Starting Page | 767 |
| Ending Page | 771 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1134/S0036024413050312 |
| Volume Number | 87 |
| Alternate Webpage(s) | https://page-one.springer.com/pdf/preview/10.1134/S0036024413050312 |
| Alternate Webpage(s) | https://doi.org/10.1134/S0036024413050312 |
| Journal | Russian Journal of Physical Chemistry A |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |