NDLI: Asymmetric epoxidation of olefins catalyzed by Ti ( salan ) complexes using aqueous hydrogen peroxide as the oxidant *

Content Provider	Semantic Scholar
Author	Matsumoto, Kazuhiro Sawada, Yuji Katsuki, Tsutomu
Copyright Year	2008
Abstract	Ti(salan) complexes were found to be efficient catalysts for asymmetric epoxidation with aqueous hydrogen peroxide as the oxidant. In the presence of pH 7.4 phosphate buffer, the reaction of various conjugate olefins proceeded smoothly to afford the corresponding epoxides in high yield with high enantioselectivity, even on a multigram scale. Ti(salan) complexes could be prepared from Ti(OiPr)4 and the corresponding salan ligand and directly used without isolation and purification.
File Format	PDF HTM / HTML
Alternate Webpage(s)	https://www.iupac.org/publications/pac/pdf/2008/pdf/8005x1071.pdf
Language	English
Access Restriction	Open
Subject Keyword	Alkenes Epoxy Compounds Hydrogen Peroxide Immunostimulating conjugate (antigen) Ligands Oxidants PHOSPHATE BUFFERS Peroxides Purification of quantum state Smoothing inorganic phosphate titanium isopropoxide
Content Type	Text
Resource Type	Article

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