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A photoinduced mixed-valence state in an organic bis-triarylamine mixed-valence compound with an iridium-metal-bridge.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Lambert, Christoph Wagener, Richard Klein, Johannes H. Grelaud, Guillaume Moos, Michael Dipl Biol Schmiedel, Alexander Holzapfel, Michael Dr. Bruhn, Torsten |
| Copyright Year | 2014 |
| Abstract | Upon irradiation a mixed-valence (MV) state is formed in a donor-iridium(III)-acceptor triad by a photoinduced electron transfer process. The resulting radical and intervalence charge transfer (IV-CT) absorptions cover a wide spectral range (3200-400 nm). These results were supported by spectroelectrochemistry, fs-time resolved pump-probe spectroscopy and assisted by TD-DFT calculations. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c4cc04885g |
| PubMed reference number | 25164489 |
| Journal | Medline |
| Volume Number | 50 |
| Issue Number | 77 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cc/c4/c4cc04885g/c4cc04885g1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/c4cc04885g |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |