Synthesis of Organometallic Cobalt(III)-, Iridium(III)- und Ruthenium(II) Complexes with a-Iminocarboxylate Ligands

Content Provider	Semantic Scholar
Author	Severin, Kay Bergs, Ralph Maurus, Michael Mihan, Shahram Beck, Wolfgang
Copyright Year	1995
Abstract	Synthese metallorganischer Cobalt(III)-, Iridium(III)und Ruthenium(II)-Komplexe mit a-Iminocarboxylat-Liganden Metal Complexes of Biologically Important Ligands, LXXV [1] Synthesis of Organometallic Cobalt(III), Iridium(III) and Ruthenium(II) Complexes with a-Iminocarboxylate Ligands Kay Severin, Ralph Bergs, Michael Maurus, Sharam Mihan [2], Wolfgang Beck+ Institut für Anorganische Chemie der Universität München, Meiserstraße 1, D-80333 München Herrn Prof. Dr. H. Schmidbaur zum 60. Geburtstag gewidmet Z. Naturforsch. 50b, 265-274 (1995); eingegangen am 26. August 1994 Cobalt, Iridium, Ruthenium, 2-Iminocarboxylate, Hydride The a-iminocarboxylato chelate complexes RuH(CO)[OOC-C(R1)= N -R 2](PPh3)2 (1), >76-/>-cymene)RuCl[00C-C(R)=N-CH2C 0 2Me] (3) and Cp*CoI[OOC-C(R1)= N -R 2] (4) have been obtained from RuHCl(CO)(PPh3)3, [(^6-p-cymene)RuCl2] and Cp*Co(CO)I2, respectively and 2-oxocarboxylate/amine. The structure of (?76-p-cym ene)RuCl[00C-C(CH3)=N -C H 2C 0 2Me] (3a) has been determined by X-ray diffraction. By use of diamines the corresponding dinuclear cobalt and iridium complexes (5, 6) are formed from 2-oxocarboxylate and Cp*Co(CO)I2 or [Cp*IrCl2]2.
Starting Page	265
Ending Page	274
Page Count	10
File Format	PDF HTM / HTML
DOI	10.1515/znb-1995-0220
Alternate Webpage(s)	http://zfn.mpdl.mpg.de/data/Reihe_B/50/ZNB-1995-50b-0265.pdf
Alternate Webpage(s)	https://doi.org/10.1515/znb-1995-0220
Volume Number	50
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article