NDLI: Design, mesomorphic properties, and supramolecular organization of (60)fullerene-containing thermotropic liquid crystals

Content Provider	Semantic Scholar
Author	Chuard, Thierry Deschenaux, Robert
Copyright Year	2002
Abstract	Two concepts have been developed for the design of [60]fullerene-containing thermotropic liquid crystals, namely, the covalent and non-covalent concepts. In the covalent approach, C60 was functionalized with liquid-crystalline addends (malonate and aldehyde derivatives) by applying either the Bingel reaction or the 1,3-dipolar cycloaddition reaction. In the non-covalent approach, a liquid-crystalline inclusion complex was obtained from mesomorphic cyclotriveratrylene (CTV) derivatives and C60. All of the covalent C60 derivatives showed smectic A phases. In one case, an additional nematic phase was detected. The [C60⊂(CTV)2] complex gave rise to nematic-like and cubic phases. The covalent and non-covalent approaches demonstrate the various possibilities for C60 to give rise to mesomorphic materials.
Starting Page	1944
Ending Page	1951
Page Count	8
File Format	PDF HTM / HTML
DOI	10.1039/B201353N
Volume Number	12
Alternate Webpage(s)	http://doc.rero.ch/record/17421/files/Chuard_Thierry_-_Design_mesomorphic_properties_and_supramolecular_20100305.pdf
Alternate Webpage(s)	https://doi.org/10.1039/B201353N
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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