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Effect of Added Surfactants on the Dynamic Interfacial Tension Behaviour of Alkaline / Diluted Heavy Crude Oil System
| Content Provider | Semantic Scholar |
|---|---|
| Author | Trabelsi, Siwar Hutin, Alice Dalmazzone, Christine Bazin, Brigitte Langevin, Dominique |
| Copyright Year | 2013 |
| Abstract | Effect of Added Surfactants on the Dynamic Interfacial Tension Behaviour of Alkaline/Diluted Heavy Crude Oil System — This study has been undertaken to get a better understanding of the interactions between Enhanced Oil Recovery (EOR) surfactants used in chemical flooding and in situ surfactants present in an heavy oil. We report an experimental study of dynamic Interfacial Tension (IFT) behaviour of diluted heavy oil/surfactant enhanced-alkaline systems. The dynamic IFT was measured using pendant drop and spinning drop tensiometers. The dynamic IFT between diluted heavy oil and alkaline solution (pH 11) with no added surfactant increased sharply with time, which was attributed to the transfer of the in situ surfactant (produced by saponification of the acids groups present in the crude oil) across the oil/water interface. The addition of Sodium Dodecyl Benzene Sulfonate (SDBS) above the Critical Micellar Concentration (CMC ~ 0.002%), changed completely the dynamic IFT behaviour of the diluted heavy oil as the IFT strongly decreased and finally reached a plateau, of about 1.5×10 mN/m at a concentration of only 0.02%. We attributed the efficiency of SDBS to a synergistic effect between the in situ surfactant and the added surfactant that form a mixed interfacial monolayer, which is very efficient in decreasing the IFT to ultra low values and in resisting mass transfer across the oil/water interface. Oil & Gas Science and Technology – Rev. IFP Energies nouvelles Copyright © 2013, IFP Energies nouvelles DOI: 10.2516/ogst/2012033 Challenges and New Approaches in EOR Défis et nouvelles approches en EOR Do s s i e r Oil & Gas Science and Technology – Rev. IFP Energies nouvelles 2 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://hal-ifp.archives-ouvertes.fr/hal-00815900/document |
| Alternate Webpage(s) | http://hal.inria.fr/docs/00/81/59/00/PDF/ogst110218-Trabelsi.pdf |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Aperture grille Copyright Digital Object Identifier ER-overload response Energy, Physics European ordering rules Experiment Floods Interaction Interface Device Component Interfacial Force Intermediate Filament Proteins Mineral Oil 1000 MG/ML Enema Pendant Dosage Form Petroleum Salicylic Acid 20 MG/ML Medicated Liquid Soap Synergy Tension Headache Transcutaneous electrical nerve stimulation sodium dodecylbenzenesulfonate |
| Content Type | Text |
| Resource Type | Article |