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Iridium(iii) hydrido complexes for the catalytic dehydrogenation of hydrazine borane.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Han, Delong Joksch, Markus Klahn, Marcus Spannenberg, Anke Drexler, H-J Baumann, Wolfgang Jiao, H. Knitsch, Robert Hansen, Mette Reimert Eckert, Hellmut Beweries, Torsten |
| Copyright Year | 2016 |
| Abstract | The synthesis of 3,5-disubstituted cyclometalated iridium(iii) hydrido complexes of the type [3,5-R2(POCOP)IrHX] (3,5-R2(POCOP) = κ3-C5HR2-2,6-(OPtBu2)2 with R = t-Bu, COOMe; X = Cl, H) is described. All complexes were investigated in the catalytic dehydrogenation of hydrazine borane and compared with the unsubstituted compounds [(POCOP)IrHX] (X = Cl, H). All catalysts are highly active and recyclable, clearly maintaining hydrogen production activity. The dehydrogenation products were structurally characterised by solid state NMR and FTIR spectroscopy. Experimental observations were complemented by a dispersion-corrected DFT study to rationalise the mechanism of hydrazine borane dehydrogenation. |
| Starting Page | 17697 |
| Ending Page | 17704 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C6DT03068H |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c6/dt/c6dt03068h/c6dt03068h1.pdf |
| PubMed reference number | 27757470 |
| Alternate Webpage(s) | https://doi.org/10.1039/C6DT03068H |
| Journal | Medline |
| Volume Number | 45 |
| Issue Number | 44 |
| Journal | Dalton transactions |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
