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Triggering dissymmetry in achiral dye molecules by chiral solvents: Circular dichroism experiments and DFT calculations.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Abbate, Sergio Longhi, Giovanna Passarello, Marco Liveri, Vincenzo Turco |
| Copyright Year | 2011 |
| Abstract | The electronic circular dichroism spectra of achiral product "Lumogen F Red" (ROT-300) in four different chiral solvents are recorded at different temperatures. DFT calculations allow to identify two enantiomeric conformers for ROT-300. In vacuo they are equally populated; in chiral solvents one enantiomer prevails. Thermodynamic quantities involved in the chiral preference are derived. |
| File Format | PDF HTM / HTML |
| DOI | 10.1002/chir.21012 |
| PubMed reference number | 21953775 |
| Journal | Medline |
| Volume Number | 23 |
| Issue Number | 10 |
| Alternate Webpage(s) | https://iris.unibs.it/retrieve/handle/11379/133728/4028/chirality2011-rot.pdf |
| Alternate Webpage(s) | https://doi.org/10.1002/chir.21012 |
| Journal | Chirality |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |