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Oxygen sensing via phosphorescence quenching of doped metal–organic frameworks
| Content Provider | Semantic Scholar |
|---|---|
| Author | Barrett, Seth M. Wang, Cheng Lin, Wenbin |
| Copyright Year | 2012 |
| Abstract | Three phosphorescent Ir and Ru complexes containing dicarboxylate functional groups have been doped into the framework of Zr6O4(OH)4(bpdc)6 (UiO-67, bpdc = para-biphenyldicarboxylate) to yield stable metal–organic frameworks (MOFs 1–3) which are highly porous with BET surface areas of 2568, 2292, and 1277 m2 g−1, respectively. The 3MLCT phosphorescence of 1–3 can be effectively quenched by O2 to provide an efficient method for oxygen detection. |
| Starting Page | 10329 |
| Ending Page | 10334 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C2JM15549D |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/jm/c2/c2jm15549d/c2jm15549d.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C2JM15549D |
| Volume Number | 22 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |