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Large-scale structure in gels of attractive block copolymer micelles.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Crichton, Mark A. Bhatia, Surita R. |
| Copyright Year | 2005 |
| Abstract | We have used ultra-small-angle scattering (USANS) and fluorescence microscopy to demonstrate the existence of a nonfractal large-scale structure in attractive micellar gels of poly(styrene)-poly(acrylic acid) block copolymers, which have some characteristics of attractive colloidal glasses. The nature of the large-scale structure appears to depend systematically on the strength of attraction. Our systems display scattering that follows I approximately q(x) in the low q regime, with x varying from approximately -3 to -4 as the strength of attraction is decreased. This scattering behavior appears to be the result of surface scattering from large, highly polydisperse aggregates with rough interfaces. |
| Starting Page | 563 |
| Ending Page | 566 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://www.ncnr.nist.gov/programs/sans/pdf/publications/0439.pdf |
| PubMed reference number | 16229523v1 |
| Volume Number | 21 |
| Issue Number | 22 |
| Journal | Langmuir : the ACS journal of surfaces and colloids |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Colloids Copolymer Gel Kinetics Microscopy, Fluorescence Non-Small Cell Lung Carcinoma Polyelectrolytes Scattering, Small Angle Thioctic Acid |
| Content Type | Text |
| Resource Type | Article |