Loading...
Please wait, while we are loading the content...
Similar Documents
Template-directed olefin cross metathesis.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Cantrill, Stuart J. Grubbs, Robert H. Lanari, Daniela Leung, Ken C-F Nelson, Alshakim Poulin-Kerstien, Katherine G. Smidt, Sebastian Peer Stoddart, J. Fraser Tirrell, David A. |
| Copyright Year | 2005 |
| Abstract | [reaction: see text] A template containing two secondary dialkylammonium ion recognition sites for encirclement by olefin-bearing dibenzo[24]crown-8 derivatives has been used to promote olefin cross metatheses with ruthenium-alkylidene catalysts. For monoolefin monomers, the rates of metatheses and yields of the dimers are both amplified in the presence of the template. Likewise, for a diolefin monomer, the yield of the dimer is enhanced in the presence of the template under conditions where higher oligomers are not formed. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/ol051599g |
| PubMed reference number | 16146390 |
| Journal | Medline |
| Volume Number | 7 |
| Issue Number | 19 |
| Alternate Webpage(s) | http://authors.library.caltech.edu/53275/1/242-Poulin.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/ol051599g |
| Journal | Organic letters |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
