Loading...
Please wait, while we are loading the content...
Similar Documents
How does the strength of the Fe-Solvent bond affect the formation of 1Fe(CO)4(solvent)
| Content Provider | Semantic Scholar |
|---|---|
| Author | Cowan, Alexander J. |
| Copyright Year | 2005 |
| Abstract | 14.Xe 125° Introduction The photochemistry of Fe(CO)5 has been studied as a model system for spin changes in organometallic systems. It was shown over 30 years ago that photolysis of Fe(CO)5 in cryogenic (12K) matrices generates the triplet intermediate, Fe(CO)4, which could be converted to Fe(CO)4(CH4) in CH4 matrices. Photolysis of Fe(CO)5 in Ar matrices generates only Fe(CO)4 without any evidence for Fe(CO)4Ar, but doping the Ar matrices with either CH4 or Xe allowed Fe(CO)4 to be converted to Fe(CO)4(CH4) or Fe(CO)4Xe, Scheme 1. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://www.clf.stfc.ac.uk/Pages/ar04-05_s5_how_does_strength.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |