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Crystallography and magnetism of radicals with hindered hydroxyl groups: 2-(3,5-di-tert-butyl-4-hydroxyphenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl and 2-(3,5-di-tert-butyl-4-hydroxyphenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Taylor, Patrick V. Lahti, Paul M. |
| Copyright Year | 2004 |
| Abstract | Radicals form networks of OH... ON and OH...Me(nitroxide) interactions. In 2, a frustrated network forms with insufficient N-O units to form extended chain interactions. The magnetism of 1 fits a 1-D Heisenberg model with J/k=-25 J mol(-1), while 2 shows more complex exchange behaviour consistent with its disordered crystal lattice. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/B411574K |
| PubMed reference number | 15568068 |
| Journal | Medline |
| Volume Number | 23 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cc/b4/b411574k/b411574k.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/B411574K |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |