NDLI: Template polymerization of N‐vinylimidazole along poly(methacrylic acid) in water. VI. Crosslinked PMAA as template

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Template polymerization of N‐vinylimidazole along poly(methacrylic acid) in water. VI. Crosslinked PMAA as template

Content Provider	Semantic Scholar
Author	Grampel, Hendrik Theodorus Van De Santing, A. G. M. Tan, Y. Yong Challa, Ger
Copyright Year	1992
Abstract	The effect of crosslinked poly (methacrylic acid) (c-PMAA) on the polymerization of N-vinylimidazole in aqueous solution was studied using UV, calorimetry, SEM, and TEM. It was established that synthetic lightly crosslinked PMAA samples behaved intermediate between rigid crosslinked PMAA particles functioning as microreactors, and linear conventional PMAA, where template and conventional polymerization in the surrounding solution are integrated. A modified calorimetric technique was used to measure monomer conversion, and to correct for the rapid adsorption process. Rate enhancements up to a factor of 4 were obtained for the c-PMAA's, which were lower than those obtained for linear conventional PMAA, and which slightly decreased with increasing crosslink density of the samples. Template complexes possessed a platelet-like morphology similar to template complexes obtained for linear PMAA.
Starting Page	787
Ending Page	796
Page Count	10
File Format	PDF HTM / HTML
DOI	10.1002/pola.1992.080300508
Volume Number	30
Alternate Webpage(s)	https://www.rug.nl/research/portal/files/3359100/titlecon.pdf
Alternate Webpage(s)	https://doi.org/10.1002/pola.1992.080300508
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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