NDLI: Carbo-deoxygenation of Biomass: The Carbonylation of Glycerol and Higher Poly-ols to Mono-carboxylic Acids

Content Provider	Semantic Scholar
Author	Coskun, Timur Conifer, Christopher M. Stevenson, Laura C. P. George J. Britovsek
Copyright Year	2014
Abstract	Glycerol is converted to a mixture of butyric and iso-butyric acid via the rhodium or iridium catalysed carbonylation using HI as the co-catalyst. The initial reaction of glycerol with HI results in several intermediates that lead to isopropyl iodide, which upon carbonylation forms butyric and isobutyric acid. At low HI concentration, the intermediate allyl iodide undergoes carbonylation to give vinyl acetic acid and crotonic acid. Higher poly-ols CnHn+2(OH)n are carbonylated to the corresponding Cn+1 mono-carboxylic acids.
File Format	PDF HTM / HTML
Alternate Webpage(s)	https://core.ac.uk/download/pdf/76992085.pdf
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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