NDLI: Compatibility between the cysteine-cyclopentenedione reaction and the copper(i)-catalyzed azide-alkyne cycloaddition.

Content Provider	Semantic Scholar
Author	Agramunt, Jordi Saltor, Laia Pedroso, Enrique Grandas, Anna
Copyright Year	2018
Abstract	The cysteine-cyclopentenedione reaction can be combined with the copper(i)-catalyzed azide-alkyne cycloaddition provided that the former is carried out first. If not, the azide and the cyclopentenedione undergo a 1,3-dipolar cycloaddition, which furnishes triazole-containing compounds and products resulting from nitrogen loss. Both of these products were fully characterized. Attempts to obtain either of them as the main compound or to drive the reaction nearly to completion were unsuccessful, which points to the azide-cyclopentenedione reaction as not being useful for bioconjugation.
Starting Page	9185
Ending Page	9190
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/c8ob02451k
PubMed reference number	30457146
Journal	Medline
Volume Number	16
Issue Number	47
Alternate Webpage(s)	http://www.rsc.org/suppdata/c8/ob/c8ob02451k/c8ob02451k1.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c8ob02451k
Journal	Organic & biomolecular chemistry
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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Compatibility between the cysteine-cyclopentenedione reaction and the copper(i)-catalyzed azide-alkyne cycloaddition.