Aqua(dicyanamido-κN 1)(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)(nitrato-κ2 O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)

Content Provider	Semantic Scholar
Author	Cui, Fenghua Zhao, Pei-Zheng
Copyright Year	2011
Abstract	In the title compound, 2[Co(C(2)N(3))(NO(3))(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·2H(2)O, the Co(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, a bidentate nitrate anion, a water mol-ecule and a monodentate dicyan-amide group in a distorted octa-hedral geometry. One uncoordinated dmphen mol-ecule is situated on a crystallographic twofold axis and the asymmetric unit is completed by one water mol-ecule. In the crystal, mol-ecules form a one-dimensional framework in the [001] direction through O-H⋯N and O-H⋯O hydrogen bonds. The crystal packing is further stabilized by π-π stacking inter-actions between the dmphen rings of neighboring mol-ecules, with a centroid-centroid separation of 3.5641 (8) Å and a partially overlapped arrangement of parallel dmphen rings with a distance of 3.407 (2) Å.
Starting Page	m1341
Ending Page	m1342
Page Count	2
File Format	PDF HTM / HTML
DOI	10.1107/S1600536811035148
PubMed reference number	22065101
Journal	Medline
Volume Number	67
Alternate Webpage(s)	https://doi.org/10.1107/S1600536811035148
Journal	Acta crystallographica. Section E, Structure reports online
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article