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Poly(pyridinium phenylene)s: water-soluble N-type polymers.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Izuhara, Daisuke Swager, Timothy M. |
| Copyright Year | 2009 |
| Abstract | Poly(pyridinium phenylene) conjugated polymers are synthesized by a cross-coupling and cyclization sequence. These polyelectrolytes are freely soluble in water and display high degrees of electroactivity. When reduced (n-doped) these materials display in situ conductivities as high as 160 S/cm. The high conductivity is attributed to the planar structure that is enforced by the cyclic structures of the polymer. The electron affinities are compared to PCBM, a C(60) based n-type material. We find that these polymers undergo excited state electron transfer reactions with other donor conjugated polymers and hence may find utility in photovoltaic devices. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/ja906513u |
| PubMed reference number | 19924995 |
| Journal | Medline |
| Volume Number | 131 |
| Issue Number | 49 |
| Alternate Webpage(s) | http://dspace.mit.edu/openaccess-disseminate/1721.1/74232 |
| Alternate Webpage(s) | https://doi.org/10.1021/ja906513u |
| Journal | Journal of the American Chemical Society |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
