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Synthesis and properties of the 3-tert-butyl-7-trifluoromethyl-1,4-dihydro-1-phenyl-1,2,4-benzotriazin-4-yl radical
| Content Provider | Semantic Scholar |
|---|---|
| Author | Takahashi, Yusuke Miura, Youhei Yoshioka, Naoki |
| Copyright Year | 2015 |
| Abstract | A novel benzotriazinyl radical, 3-tert-butyl-7-trifluoromethyl-1,4-dihydro-1-phenyl-1,2,4-benzotriazin-4-yl (2), was prepared and its magneto-structural correlation was investigated. An X-ray crystallographic analysis revealed that 2 forms a 1D column assembly, however, π–π interaction was not the driving force of the column structure. The magnetic susceptibility obeyed the Curie–Weiss law with C = 0.369 emu K mol−1 and θ = +0.7 K. The thermal behavior of χmT was described using the 1D ferromagnetic chain model with J/kB = +0.91 K. |
| Starting Page | 4783 |
| Ending Page | 4789 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C5NJ00393H |
| Volume Number | 39 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c5/nj/c5nj00393h/c5nj00393h1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C5NJ00393H |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |