NDLI: Degenerate rearrangement of long-lived 9-cyclopropyl-9,10-dimethyl-9,10-dihydrophenanthren-9-ylium: Migration of cyclopropyl group

Content Provider	Semantic Scholar
Author	Genaev, Alexander M. Salnikov, Georgi E. Shubin, Vyacheslav G.
Copyright Year	2010
Abstract	Dynamic NMR study showed that long-lived 9-cyclopropyl-9,10-dimethyl-9,10-dihydrophenanthren-9-yl cation generated from 9-cyclopropyl-9,10-dimethyl-9,10-dihydrophenanthren-9-ol in HSO3F-SO2ClF-CD2Cl2 at −100 to −75°C undergoes fast degenerate 1,2-shift of the cyclopropyl group. The Arrhenius parameters for this process were determined: Ea = 33.7 kJ/mol, log A = 13.0.
Starting Page	311
Ending Page	317
Page Count	7
File Format	PDF HTM / HTML
DOI	10.1134/S1070428010030012
Volume Number	46
Alternate Webpage(s)	https://page-one.springer.com/pdf/preview/10.1134/S1070428010030012
Alternate Webpage(s)	https://doi.org/10.1134/S1070428010030012
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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