NDLI: Catalyzed formation of α,β-unsaturated ketones or aldehydes from propargylic acetates by a recoverable and recyclable nanocluster catalyst.

Content Provider	Semantic Scholar
Author	Li, Man-Bo Tian, Shi‐ Kai Wu, Zhikun
Copyright Year	2014
Abstract	An active, recoverable, and recyclable nanocluster catalyst, Au25(SR)18(-), has been developed to catalyze the formation of α,β-unsaturated ketones or aldehydes from propargylic acetates. The catalytic process has been proposed to be initialized by an SN2' addition of OH(-). Moreover, a dramatic solvent effect was observed, for which a rational explanation was provided.
File Format	PDF HTM / HTML
DOI	10.1039/c4nr00658e
PubMed reference number	24789019
Journal	Medline
Volume Number	6
Issue Number	11
Alternate Webpage(s)	http://www.rsc.org/suppdata/nr/c4/c4nr00658e/c4nr00658e1.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c4nr00658e
Journal	Nanoscale
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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