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Conversion of 2-ethyl-3,3,5,5-tetramethyl- and 2-ethyl-1,3,3,5,5-pentamethyl-1,2,4,5-tetra-hydro-3h-benz-2-azepines by the action of ethyl propiolate
| Content Provider | Semantic Scholar |
|---|---|
| Author | Voskressensky, Leonid G. Borisova, Tatiana N. Sorokina, Elena A. Kulikova, Larisa N. Kleimenov, A. V. Tolkunov, S. V. Varlamov, Alexey V. |
| Copyright Year | 2009 |
| Abstract | It has been shown that, on interacting 2-ethyl-3,3,5,5-tetramethyl- and 2-ethyl-1,3,3,5,5-pentamethyl-1,2,4,5-tetrahydro-3H-benz-2-azepines with ethyl propiolate in methanol, fission of the azepine ring occurs at the C(1)–N(2) bond involving a molecule of solvent. The indicated azepines do not react with acetylenedicarboxylic acid ester under these conditions. |
| Starting Page | 1248 |
| Ending Page | 1251 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1007/s10593-010-0414-4 |
| Volume Number | 45 |
| Alternate Webpage(s) | https://page-one.springer.com/pdf/preview/10.1007/s10593-010-0414-4 |
| Alternate Webpage(s) | https://doi.org/10.1007/s10593-010-0414-4 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |