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Stereoselective Radical C—H Alkylation with Acceptor/Acceptor-Substituted Diazoreagents via Co(II)-Based Metalloradical Catalysis.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Xu, Xue Song Wojtas, Lukasz Zhang, X. Peter |
| Copyright Year | 2015 |
| Abstract | A new chiral amidoporphyrin derivative acts as a catalyst in the intramolecular 1,5-C—H alkylation of α-methoxycarbonyl α-diazosulfones of type (I) to give chiral sulfolane derivatives of type (II) in high yields with excellent diastereoselectivities and enantioselectivities. |
| File Format | PDF HTM / HTML |
| DOI | 10.1002/chin.201523113 |
| Volume Number | 46 |
| Alternate Webpage(s) | http://pubs.rsc.org/en/content/articlepdf/2014/sc/c4sc02610a?page=search |
| Alternate Webpage(s) | https://academicworks.cuny.edu/cgi/viewcontent.cgi?article=2035&context=bb_pubs |
| Alternate Webpage(s) | https://doi.org/10.1002/chin.201523113 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |