NDLI: Application of circular dichroism spectroscopy in the study of mixed-valence asymmetric ruthenium polypyridyl complexes.

Content Provider	Semantic Scholar
Author	Ahmed, Hamid M. Younis Coburn, Nadia Dini, Danilo Jong, Jaap J. D. De Villani, Claudio Browne, Wesley R. Vos, Johannes G.
Copyright Year	2011
Abstract	Circular dichroism (CD) spectroelectrochemistry is used to determine the extent of singly occupied molecular orbital delocalization in mixed-valence multinuclear complexes, specifically the mixed-valence Ru(II)Ru(III) states of the four diastereoisomers of [(Ru(bpy)(2))(2)(bpt)](3+) [1; bpy = 2,2'-bipyridyl and bpt = 3,5-bis(pyrid-2'-yl)-1,2,4-triazolato anion]. The complex was found to be stable to thermal racemization in the three oxidation states, but photoracemization in the Ru(II)Ru(II) state was observed.
File Format	PDF HTM / HTML
DOI	10.1021/ic200633a
PubMed reference number	21627089
Journal	Medline
Volume Number	50
Issue Number	13
Alternate Webpage(s)	https://www.rug.nl/research/portal/files/10465397/2011InorgChemAhmedSupp.pdf
Alternate Webpage(s)	https://www.rug.nl/research/portal/files/10465398/2011InorgChemAhmed.pdf
Alternate Webpage(s)	https://core.ac.uk/download/pdf/12954631.pdf
Alternate Webpage(s)	https://doi.org/10.1021/ic200633a
Journal	Inorganic chemistry
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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