Metallkomplexe mit Hexamethylentetramin als Ligand, VI [1] Kristallstruktur von Bis-hexamethylentetramin-bisisocyanatokupfer(II), [CU(NCO)2(C6H12N4)2] / Metal Complexes with Hexamethylenetetramine as a Ligand, VI [1J Crystal Structure of Bis-hexamethylenetetramine-bisisocyanatocopper(II), [Cu(NCO)2(

Content Provider	Semantic Scholar
Author	Pickardt, Joachim Rautenberg, Norbert
Copyright Year	1982
Abstract	Crystals of the complex [Cu(NCO)2(C6Hi2N4)2] could be obtained by reaction of copper- (II)nitrate, hexamethylenetetramine, and KNCO in CHCI3 as a solvent. The crystals are triclinic, space group Cl, Z = 4, a = 1373.1(9), b = 2083.1(9), c = 642.6(3) pm, a = 91.05(4), β = 90.54(6), y = 107.39(6)°. The copper atom is bonded to two terminal cyanato groups via the nitrogen atoms, and to two liexamethylentetramine molecules. In the solid state the coordination of the copper atom is, however, tetragonal pyramidal, because there is an additional, rather long bond to one of the hexamethylenetetramine molecules of the neighbouring complex unit, resulting in the formation of chains
Starting Page	1569
Ending Page	1572
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1515/znb-1982-1216
Alternate Webpage(s)	http://zfn.mpdl.mpg.de/data/Reihe_B/37/ZNB-1982-37b-1569.pdf
Alternate Webpage(s)	https://doi.org/10.1515/znb-1982-1216
Volume Number	37
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article