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(2,9-Dimethyl-1,10-phenanthroline-κ2 N,N′)bis(thiocyanato-κS)mercury(II)
| Content Provider | Semantic Scholar |
|---|---|
| Author | Warad, Ismail Hadda, Taibi Ben Hammouti, Belkheir Haddad, Salim F. |
| Copyright Year | 2012 |
| Abstract | The asymmetric unit of the title compound, [Hg(SCN)(2)(C(14)H(12)N(2))], contains two complex mol-ecules in which the Hg(II) atoms are both four-coordinated in a distorted tetra-hedral configuration by two N atoms from a chelating 2,9-dimethyl-1,10-phenanthroline ligand and by two S atoms from two thio-cyanate anions. The 1,10-phenanthroline ligand is slightly folded for one complex, the dihedral angle between the pyridine planes being 5.3 (1)°. In contrast it is nearly planar [0.5 (1)°] as it complexes with the other Hg(II) atom. The thio-cyanate ligands are virtually linear and the S atom is bonded to Hg(II) with N⋯S-Hg angles ranging from 99.3 (1) to 103.5 (1)°. Despite the presence of six aromatic rings in the asymmetric unit, there are no significant inter-molecular π-π contacts between phenanthroline ligands as the centroid-centroid distance of the closest contact between six-membered rings is 4.11 (1) A°. |
| Starting Page | m1259 |
| Ending Page | m1259 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S1600536812038160 |
| PubMed reference number | 23125589 |
| Journal | Medline |
| Volume Number | 68 |
| Alternate Webpage(s) | https://staff.najah.edu/media/sites/default/files/2_9-Dimethyl-1_10-Phenanthroline-_2N_N_-Bis-Thiocyanato-_S_Mercury-II.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536812038160 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
