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Catalytic asymmetric [2,3]-sigmatropic rearrangement of sulfur ylides generated from copper(I) carbenoids and allyl sulfides.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhang, Xiaomei Qu, Zhaohui Ma, Zhihua Shi, Weifeng Jin, Xianglin Wang, Jianbo |
| Copyright Year | 2002 |
| Abstract | Catalytic asymmetric sulfur ylide [2,3]-sigmatropic rearrangement of carbenoids generated from aryldiazoacetates has been investigated with a number of chiral Rh(II) and Cu(I) catalysts, and moderately high enantioselectivity (52-78% ee) can be achieved with Cu(MeCN)(4)PF(6)/2,2'-isopropylidenebis[(4S)-4-tert-butyl-2-oxazoline]. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/jo025687f |
| PubMed reference number | 12153260 |
| Journal | Medline |
| Volume Number | 67 |
| Issue Number | 16 |
| Alternate Webpage(s) | http://www.chem.pku.edu.cn/physicalorganic/Published%20Papers/ZHANG_JOC.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/jo025687f |
| Journal | The Journal of organic chemistry |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |