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Noncovalent interactions in acid–porphyrin complexes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Webb, Matthew W. J. Bampos, Nick |
| Copyright Year | 2012 |
| Abstract | This report examines the dynamics and the complexation behaviour of ‘acid porphyrin’ systems in solution and provides a valuable insight into the mechanisms for both porphyrin protonation and metallation. The synthesis of mono- and bis-substituted porphyrins appended with long alkyl chain fluorinated acids permitted intramolecular proton transfer to be observed and macrocyclic conformational control to be achieved. Furthermore, acid–porphyrin complexation is shown to be compatible with established metal–ligand interactions in the generation of novel supramolecular assemblies in solution. |
| Starting Page | 2351 |
| Ending Page | 2366 |
| Page Count | 16 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C2SC20271A |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/sc/c2/c2sc20271a/c2sc20271a.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C2SC20271A |
| Volume Number | 3 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
