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An unprecedented Co(II) cuboctahedron as the secondary building unit in a Co-based metal-organic framework.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Holmberg, Rebecca J. Kay, Marika Korobkov, I. V. Kadantsev, Eugene Boyd, Peter G. Aharen, Tomoko Desgreniers, Serge Murugesu, Muralee |
| Copyright Year | 2014 |
| Abstract | A cubic metal-organic framework with an unprecedented octanuclear secondary building unit (SBU) was isolated. The obtained SBU is composed of 8 Co(II) ions at each vertex, 6 μ4-OH groups at each face, and 12 cpt(-) ligands framing the metal core. The cuboctahedra arrange in a ubt framework topology, eliciting a highly symmetrical MOF structure. Magnetic measurements as well as DFT calculations on this crystalline MOF reveal intramolecular antiferromagnetic coupling between Co(II) ions in the octanuclear SBU. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c3cc46396f |
| PubMed reference number | 24162794 |
| Journal | Medline |
| Volume Number | 50 |
| Issue Number | 40 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cc/c3/c3cc46396f/c3cc46396f.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/c3cc46396f |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
