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Laser photodissociation spectroscopy of mass-selected metal clusters
| Content Provider | Semantic Scholar |
|---|---|
| Author | Willey, Kenneth F. Robbins, David L. Yeh, Chen-Sheng Duncan, Michael A. |
| Copyright Year | 1991 |
| Abstract | Electronic spectra are reported for the metal cluster (Te+2) and metal cluster complex (Ag+–benzene, Mg+–CO2) cations. These ions are generated by laser vaporization in a pulsed nozzle source, jet-cooled, mass-selected with a reflectron time-of-flight spectrometer, and dissociated on resonance with a tunable dye laser. Electronic excitation spectra are recorded by monitoring the appearance of the fragment-ion channel(s) as the dissociation laser is tuned through electronic and/or vibronic resonances. Analysis of these new spectra yields vibrational constants, binding energetics and evidence for new photochemistry in these novel ion systems. |
| Starting Page | 269 |
| Ending Page | 277 |
| Page Count | 9 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/FD9919200269 |
| Alternate Webpage(s) | http://kicp.uchicago.edu/~odom/molecule_database/Te2/ion%20gs%20vibrational%20constants.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/FD9919200269 |
| Volume Number | 92 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
